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Some have to an extent, species of jumping spider have fluorescing areas ( pedipalps, femor undersides, ventral areas etc) that they use in their mating rituals, it is usually the fine hairs that fluoresce and not the exoskeleton.
there isn't, to my knowledge, a spider that has an all over exoskeletal irredescence similar to a scorpion.
Don't forget to learn what you can, when you can, where you can.
Some recent research has further fortified the fact that over exposure to artificial ultra violet lighting (of all wavelengths) can be harmful to scorpions ( including feeding habits, moulting, mating habits) so checking with a low intensity UV light to find them is still ok, but having hours of fluorescing animals walking around a tank is more of a no no than originally thought.
Don't forget to learn what you can, when you can, where you can.
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